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The ionization energy is the energy needed to remove an electron from an atom. In the Bohr model of the hydrogen atom, this means exciting the electron to the n = ∞ state. What is the ionization energy in kJ/mol, for hydrogen atoms initially in the n = 2 energy level?


A) 290 kJ/mol
B) 328 kJ/mol
C) 656 kJ/mol
D) 983 kJ/mol
E) 1311 kJ/mol

F) C) and E)
G) C) and D)

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Select the arrangement of electromagnetic radiation which starts with the lowest wavelength and increases greatest wavelength.


A) radio, infrared, ultraviolet, gamma rays
B) radio, ultraviolet, infrared, gamma rays
C) gamma rays, radio, ultraviolet, infrared
D) gamma rays, infrared, radio, ultraviolet
E) gamma rays, ultraviolet, infrared, radio

F) A) and B)
G) A) and C)

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Who proposed the principle that states that one cannot simultaneously know the exact position and velocity of a particle?


A) Einstein
B) Planck
C) Heisenberg
D) Compton
E) de Broglie

F) None of the above
G) B) and E)

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An electron in the n = 6 level emits a photon with a wavelength of 410.2 nm. To what energy level does the electron move?


A) n = 1
B) n = 2
C) n = 3
D) n = 4
E) n = 5

F) B) and C)
G) A) and B)

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A wave function for an electron is called an atomic orbital.

A) True
B) False

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The FM station KDUL broadcasts music at 99.1 MHz. Find the wavelength of these waves.


A) 1.88 × 10-2 m
B) 0.330 m
C) 3.03 m
D) 5.33 × 102 m
E) > 103 m

F) A) and B)
G) C) and D)

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As the frequency of electromagnetic radiation increases, its wavelength also increases.

A) True
B) False

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Which scientist demonstrated that photons transferred momentum during collisions with matter?


A) Bohr
B) de Broglie
C) Planck
D) Compton
E) Billiard

F) A) and C)
G) A) and B)

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Who developed an empirical equation from which the wavelengths of lines in the spectrum of hydrogen atoms can be calculated?


A) Planck
B) de Broglie
C) Bohr
D) Rutherford
E) Rydberg

F) A) and E)
G) A) and D)

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According to the Heisenberg uncertainty principle, if the uncertainty in the speed of an electron is 3.5 × 103 m/s, the uncertainty in its position (in m) is at least


A) 1.7 × 10-8 m.
B) 6.6 × 10-8 m.
C) 17 m.
D) 66 m.
E) None of these choices are correct.

F) A) and B)
G) A) and E)

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Interference of light waves


A) separates light into its component colors.
B) creates a pattern of light and dark regions.
C) focuses a broad beam of light into a point.
D) bends light as it passes the edge of an object.
E) creates a laser beam.

F) B) and E)
G) A) and C)

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The Bohr theory of the hydrogen atom predicts the energy difference (in J) between the n = 3 and the n = 5 state to be


A) 8.72 × 10-20 J.
B) 1.36 × 10-19 J.
C) 2.42 × 10-19 J.
D) 1.55 × 10-19 J.
E) 1.09 × 10-18 J.

F) D) and E)
G) A) and B)

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According to the Rydberg equation, the longest wavelength (in nm) in the series of H-atom lines with n1 = 3 is


A) 1875 nm.
B) 1458 nm.
C) 820. nm.
D) 656 nm.
E) 365 nm.

F) A) and B)
G) A) and C)

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An infrared wave has a wavelength of 6.5 × 10-4 cm. What is this distance in angstroms, Å?


A) 6.5 × 10-4 Å
B) 2.2 × 10-4 Å
C) 4.6 × 103 Å
D) 6.5 × 104 Å
E) 6.5 × 106 Å

F) B) and E)
G) A) and B)

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Consider the following adjectives used to describe types of spectrum: Continuous line atomic emission absorption How many of them are appropriate to describe the spectrum of radiation absorbed by a sample of mercury vapor?


A) one
B) two
C) three
D) four
E) five

F) B) and D)
G) C) and D)

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Who was the first scientist to propose that the atom had a dense nucleus that occupied only a small fraction of the volume of the atom?


A) Planck
B) Bohr
C) Rydberg
D) Rutherford
E) Thomson

F) C) and E)
G) B) and C)

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The energy of an electron in the hydrogen atom is determined by


A) the principal quantum number (n) only.
B) the angular momentum quantum number (l) only.
C) the principal and angular momentum quantum numbers (n & l ) .
D) the principal and magnetic quantum numbers (n & ml) .
E) the principal, angular momentum and magnetic quantum numbers.

F) B) and D)
G) B) and C)

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The Rydberg equation is an example of an empirical equation.

A) True
B) False

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The interference pattern seen when light passes through narrow, closely spaced slits, is due to


A) diffraction.
B) reflection.
C) refraction.
D) dispersion.
E) deflection.

F) C) and D)
G) C) and E)

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Contact lenses can focus light due to the ____________ of the waves.


A) diffraction
B) reflection
C) refraction
D) dispersion
E) interference

F) A) and B)
G) A) and C)

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