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Which of the following sets of elements have the [noble gas]ns2np2 valence electron configuration?


A) O, S, Se, Te, Po
B) N, P, As, Sb, Bi
C) F, Cl, Br, I, At
D) C, Si, Ge, Sn, Pb
E) Ti, Zr, Hf

F) B) and D)
G) C) and E)

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In neutral atoms, the 3d orbitals have higher energy than the 4s orbitals.

A) True
B) False

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Describe how the ionization energies of main group elements vary across a period in the periodic table, using a diagram if necessary.

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Ionization energies generally ...

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Select the correct set of quantum numbers (n, l, ml, ms) for the highest energy electron in the ground state of tin, Sn.


A) 5, 2, -1, ½
B) 5, 2, 0, ½
C) 5, 1, 2, ½
D) 5, 1, 0, ½
E) 5, 2, 1, ½

F) A) and E)
G) B) and E)

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Which of the following sublevels is filled last?


A) 3d
B) 4s
C) 4p
D) 4d
E) 5s

F) D) and E)
G) B) and C)

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D

Which of the following atoms will be diamagnetic?


A) Cr
B) Ru
C) Fe
D) Pt
E) Cd

F) A) and D)
G) B) and E)

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Which one of the following statements about orbital energies is incorrect?


A) In the hydrogen atom, the energy of an orbital depends only on the value of the quantum number n.
B) In many-electron atoms the energy of an orbital depends on both n and l.
C) Inner electrons shield outer electrons more effectively than do electrons in the same orbital.
D) The splitting of sublevels in many-electron atoms is explained in terms of the penetration effect.
E) The energy of a given orbital increases as the nuclear charge Z increases.

F) B) and D)
G) B) and E)

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E

Which of the following elements has the largest atomic size?


A) S
B) Ca
C) Ba
D) Po
E) Rn

F) None of the above
G) A) and E)

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Which of the following electron configurations is impossible?


A) 1s22s22p63s23p4
B) 1s22s22p53s13p4
C) 1s22s22p63s23p63d104s2
D) 1s22s22p63s33p4
E) 1s12s22p63s23p4

F) D) and E)
G) B) and C)

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Select the paramagnetic ion.


A) Cu+
B) Ag+
C) Fe3+
D) Cd2+
E) Ca2+

F) A) and E)
G) A) and D)

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Select the element with the most negative electron affinity (i.e., accepts an electron most readily) .


A) H
B) Li
C) C
D) F
E) Ne

F) B) and D)
G) B) and C)

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The most acidic oxides are formed from elements found in the _________________ region of the periodic table.


A) upper right
B) upper left
C) center
D) lower right
E) lower left

F) C) and E)
G) B) and D)

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A

Select the most basic compound from the following:


A) Bi2O3
B) SiO2
C) Cs2O
D) Na2O
E) H2O

F) B) and E)
G) A) and B)

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Which one of the following equations correctly represents the process involved in the electron affinity of X?


A) X(g) \rightarrow X+(g) + e¯
B) X+(g) \rightarrow X+(aq)
C) X+(g) + e¯ \rightarrow X(g)
D) X(g) + e¯ \rightarrow X¯(g)
E) X+(g) + Y¯(g) \rightarrow XY(s)

F) A) and B)
G) C) and D)

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In moving down a group in the periodic table, the oxides of the elements become more acidic in nature.

A) True
B) False

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Define what is meant by ionization energy, and write a balanced chemical equation to represent the relevant process for element X.

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Ionization energy is the minim...

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Bigger atoms generally have smaller ionization energies.

A) True
B) False

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Select the element with the least metallic character.


A) Sn
B) Sr
C) Tl
D) Ge
E) Ga

F) None of the above
G) All of the above

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Which of the following elements has the largest first ionization energy?


A) Na
B) Cl
C) Ca
D) Te
E) Br

F) B) and D)
G) A) and B)

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Which of the following has the most negative electron affinity?


A) H
B) Li
C) Na
D) K
E) Rb

F) None of the above
G) A) and D)

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