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What mass of copper will be deposited when 18.2 A are passed through a CuSO4 solution for 45.0 minutes?


A) 16.2 g
B) 33.4 g
C) 40.6 g
D) 81.3 g
E) 163 g

F) A) and B)
G) D) and E)

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Consider the following balanced redox reaction Mn2+(aq) + S2O82¯(aq) + 2H2O(l) \rightarrow MnO2(s) + 4H+(aq) + 2SO42¯(aq) Which of the following statements is true?


A) Mn2+(aq) is the oxidizing agent and is reduced.
B) Mn2+(aq) is the oxidizing agent and is oxidized.
C) Mn2+(aq) is the reducing agent and is oxidized.
D) Mn2+(aq) is the reducing agent and is reduced.
E) Manganese does not change its oxidation number in this reaction.

F) A) and C)
G) A) and E)

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Two cells are connected in series, so that the same current flows through two electrodes where the following half-reactions occur Cu2+(aq) + 2e¯ \rightarrow Cu(s) and Ag+(aq) + e¯ \rightarrow Ag(s) For every 1.00 g of copper produced in the first process, how many grams of silver will be produced in the second one?


A) 0.294 g
B) 0.588 g
C) 0.850 g
D) 1.70 g
E) 3.40 g

F) B) and E)
G) B) and C)

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A voltaic cell consists of a Hg/Hg22+ electrode (E °\degree = 0.85 V) and a Sn/Sn2+ electrode (E °\degree = -0.14 V) . Calculate [Sn2+] if [Hg22+] = 0.24 M and Ecell = 1.04 V at 25 °\degree C.


A) 0.0001 M
B) 0.0007 M
C) 0.005 M
D) 0.03 M
E) 0.05 M

F) A) and E)
G) B) and C)

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In a fuel cell, an external source of electrical power is used to drive a non-spontaneous reaction in which a fuel is produced.

A) True
B) False

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What is the value of the equilibrium constant for the cell reaction below at 25 °\degree C? E °\degree cell = 0.61 V 2Cr(s) + 3Pb2+(aq)  What is the value of the equilibrium constant for the cell reaction below at 25 \degree C?  E \degree <sub>cell</sub> = 0.61 V 2Cr(s)  + 3Pb<sup>2+</sup>(aq)    3Pb(s)  + 2Cr<sup>3+</sup>(aq)  A)  4.1 * 10<sup>20</sup> B)  8.2 * 10<sup>30</sup> C)  3.3* 10<sup>51</sup> D)  7.4 * 10<sup>61</sup> E)  > 9.9 *10<sup>99</sup> 3Pb(s) + 2Cr3+(aq)


A) 4.1 * 1020
B) 8.2 * 1030
C) 3.3* 1051
D) 7.4 * 1061
E) > 9.9 *1099

F) B) and E)
G) A) and B)

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Examine the following half-reactions and select the strongest oxidizing agent among the substances. Examine the following half-reactions and select the strongest oxidizing agent among the substances.   A)  [PtCl<sub>4</sub>]<sup>2</sup>¯(aq)  B)  RuO<sub>4</sub>(s)  C)  HFeO<sub>4</sub>¯(aq)  D)  H<sub>4</sub>XeO<sub>6</sub>(aq)  E)  Cl¯(aq)


A) [PtCl4]2¯(aq)
B) RuO4(s)
C) HFeO4¯(aq)
D) H4XeO6(aq)
E) Cl¯(aq)

F) C) and E)
G) C) and D)

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A solution is prepared by dissolving 32.0 g of NiSO4 in water. What current would be needed to deposit all of the nickel in 5.0 hours?


A) 1.1 A
B) 2.2 A
C) 3.3 A
D) 4.4 A
E) 5.5 A

F) A) and B)
G) B) and D)

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Consider the following balanced redox reaction 3CuO(s) + 2NH3(aq) \rightarrow N2(g) + 3H2O(l) + 3Cu(s) Which of the following statements is true?


A) CuO(s) is the oxidizing agent and copper is reduced.
B) CuO(s) is the oxidizing agent and copper is oxidized.
C) CuO(s) is the reducing agent and copper is oxidized.
D) CuO(s) is the reducing agent and copper is reduced.
E) CuO(s) is the oxidizing agent and N2(g) is the reducing agent.

F) D) and E)
G) B) and D)

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Examine the following half-reactions and select the strongest reducing agent among the species listed. Examine the following half-reactions and select the strongest reducing agent among the species listed.   A)  Pb(s)  B)  Ca(s)  C)  Pt(s)  D)  Br¯(aq)  E)  Pt<sup>2+</sup>(aq)


A) Pb(s)
B) Ca(s)
C) Pt(s)
D) Br¯(aq)
E) Pt2+(aq)

F) B) and D)
G) B) and C)

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A battery that cannot be recharged is a


A) fuel cell.
B) primary battery.
C) secondary battery.
D) simple battery.
E) flow battery.

F) A) and C)
G) B) and E)

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Examine the following half-reactions and select the weakest reducing agent among the substances. Examine the following half-reactions and select the weakest reducing agent among the substances.   A)  Cr(s)  B)  Sn(s)  C)  Mn<sup>2+</sup>(aq)  D)  Hg(l)  E)  OH¯(aq)


A) Cr(s)
B) Sn(s)
C) Mn2+(aq)
D) Hg(l)
E) OH¯(aq)

F) A) and D)
G) C) and E)

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What is the E °\degree cell for the cell represented by the combination of the following half-reactions?  What is the E \degree <sub>cell</sub> for the cell represented by the combination of the following half-reactions?   A)  -0.18 V B)  0.18 V C)  1.28 V D)  1.66 V E)  2.12 V


A) -0.18 V
B) 0.18 V
C) 1.28 V
D) 1.66 V
E) 2.12 V

F) A) and E)
G) A) and B)

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Calculate E °\degree cell for the reaction of nickel(II) ions with cadmium metal at 25 °\degree C. K = 1.17 *105. Ni2+(aq) + Cd(s) \rightarrow Cd2+(aq) + Ni(s)


A) 0.075 V
B) 0.10 V
C) 0.12 V
D) 0.15 V
E) 0.30 V

F) C) and D)
G) All of the above

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The redox reaction of peroxydisulfate with iodide has been used for many years as part of the iodine clock reaction which introduces students to kinetics. If E °\degree cell = 1.587 V and E °\degree of the cathode half-cell is 0.536 V, what is E °\degree of the anode half-cell?  The redox reaction of peroxydisulfate with iodide has been used for many years as part of the iodine clock reaction which introduces students to kinetics. If E \degree <sub>cell</sub> = 1.587 V and E \degree of the cathode half-cell is 0.536 V, what is E \degree  of the anode half-cell?   A)  -1.051 V B)  -2.123 V C)  1.051 V D)  2.123 V E)  None of these choices is correct.


A) -1.051 V
B) -2.123 V
C) 1.051 V
D) 2.123 V
E) None of these choices is correct.

F) A) and E)
G) All of the above

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What mass of silver will be formed when 15.0 A are passed through molten AgCl for 25.0 minutes?


A) 0.419 g
B) 6.29 g
C) 12.6 g
D) 25.2 g
E) 33.4 g

F) None of the above
G) A) and D)

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Consider the reaction of iodine with manganese dioxide: 3I2(s) + 2MnO2(s) + 8OH¯(aq)  Consider the reaction of iodine with manganese dioxide:  3I<sub>2</sub>(s)  + 2MnO<sub>2</sub>(s)  + 8OH¯(aq)    6I¯(aq)  + 2MnO<sub>4</sub>¯(aq)  + 4H<sub>2</sub>O(l)  The equilibrium constant for the overall reaction is 8.30* 10¯<sup>7</sup>. Calculate  \Delta G \degree  for the reaction at 25 \degree C. A)  -15.1 kJ B)  -34.7 kJ C)  15.1 kJ D)  34.7 kJ E)  None of these choices is correct. 6I¯(aq) + 2MnO4¯(aq) + 4H2O(l) The equilibrium constant for the overall reaction is 8.30* 10¯7. Calculate Δ\Delta G °\degree for the reaction at 25 °\degree C.


A) -15.1 kJ
B) -34.7 kJ
C) 15.1 kJ
D) 34.7 kJ
E) None of these choices is correct.

F) All of the above
G) A) and B)

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Consider the non-aqueous cell reaction  Consider the non-aqueous cell reaction   for which E \degree <sub>cell</sub> = 2.35 V at 200 \degree C.  \Delta G \degree at this temperature is A)  453 kJ. B)  -453 kJ. C)  907 kJ. D)  -907 kJ. E)  None of these choices is correct. for which E °\degree cell = 2.35 V at 200 °\degree C. Δ\Delta G °\degree at this temperature is


A) 453 kJ.
B) -453 kJ.
C) 907 kJ.
D) -907 kJ.
E) None of these choices is correct.

F) A) and E)
G) D) and E)

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When the following redox equation is balanced with smallest whole number coefficients, the coefficient for the iodide ion will be _____. When the following redox equation is balanced with smallest whole number coefficients, the coefficient for the iodide ion will be _____.   A)  2 B)  3 C)  6 D)  8 E)  None of these choices is correct.


A) 2
B) 3
C) 6
D) 8
E) None of these choices is correct.

F) A) and B)
G) All of the above

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A concentration cell consists of two Al/Al3+ electrodes. The electrolyte in compartment A is 0.050 M Al(NO3) 3 and in compartment B is 1.25 M Al(NO3) 3. What is the voltage of the cell at 25 °\degree C?


A) 0.083 V
B) 0.062 V
C) 0.041V
D) 0.028 V
E) None of these choices is correct.

F) A) and C)
G) A) and D)

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