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Safrole is used as a topical antiseptic. Calculate the vapor pressure of a solution prepared by dissolving 0.75 mol of safrole in 950 g of ethanol (? = 46.07 g/mol) . P °\degree ethanol = 50.0 torr at 25 °\degree C.


A) 1.8 torr
B) 11 torr
C) 15 torr
D) 40 torr
E) 48 torr

F) B) and D)
G) A) and B)

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The mole fraction of potassium nitrate in an aqueous solution is 0.0194. The solution's density is 1.0627 g/mL. Calculate the molarity of the solution.


A) 0.0194 M
B) 0.981 M
C) 1.05 M
D) 1.96 M
E) 19.4 M

F) C) and E)
G) B) and C)

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If the shell of a raw egg is carefully dissolved away, and the egg in its flexible membrane is then placed in distilled water, the egg's volume will expand. Explain.

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The osmotic pressure of the solution ins...

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Classify the following as either solutions or colloids. If a colloid, name the type of colloid and identify both the dispersed and the dispersing phases. a. glucose in water b. smoke in air c. carbon dioxide in air d. milk

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a. solution
b. coll...

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Carbon tetrachloride, once widely used in fire extinguishers and as a dry cleaning fluid, has been found to cause liver damage to those exposed to its vapors over long periods of time. What is the boiling point of a solution prepared by dissolving 375 g of sulfur (S8, ? = 256.5 g/mol) in 1250 g of CCl4? Kb = 5.05 °\degree C/m, boiling point of pure CCl4 = 76.7 °\degree C


A) 70.8 °\degree C
B) 75.2 °\degree C
C) 78.2 °\degree C
D) 82.6 °\degree C
E) >85 °\degree C

F) A) and B)
G) All of the above

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Copper(II) bromide is used as a wood preservative. What mass of CuBr2 is needed to prepare 750.0 mL of a 1.25 M solution?


A) 134 g
B) 209 g
C) 372 g
D) 938 g
E) > 1 kg

F) A) and E)
G) A) and B)

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The shape of a protein molecule is determined completely by


A) hydrogen bonding.
B) ion-dipole attractions.
C) dispersion forces.
D) disulfide bridges.
E) the sequence of amino acids in the chain.

F) A) and C)
G) C) and D)

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Which of the following aqueous solutions should demonstrate the most ideal behavior?


A) 0.1 M K2SO4
B) 0.1 M CaCl2
C) 3.0 M LiF
D) 0.1 M MgSO4
E) 0.1 M NaCl

F) B) and E)
G) B) and C)

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Under physiological conditions, amino acids in solution carry


A) no electrical charges.
B) a net positive charge, due to an -NH3+ group or groups.
C) a net negative charge, due to a -COO¯ group or groups.
D) both -NH2 and -COOH groups.
E) both -NH3+ and -COO¯ groups.

F) B) and D)
G) B) and C)

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A solution of sucrose (sugar) in water is in equilibrium with solid sucrose. If more solid sucrose is now added, with stirring,


A) the concentration of the solution will increase.
B) the concentration of the solution will decrease.
C) the concentration of the solution will remain the same.
D) the volume of solution will increase.
E) a supersaturated solution will be produced.

F) A) and D)
G) A) and E)

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The solubility of the oxidizing agent potassium permanganate is 7.1 g per 100.0 g of water at 25 °\degree C. What is the mole fraction of potassium permanganate in this solution?


A) 0.0080
B) 0.0086
C) 0.066
D) 0.45
E) 0.48

F) A) and C)
G) D) and E)

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Human blood has a molar concentration of solutes of 0.30 M. What is the osmotic pressure of blood at 25 °\degree C?


A) 0.012 atm
B) 0.62 atm
C) 6.8 atm
D) 7.3 atm
E) >10. atm

F) A) and B)
G) All of the above

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Two aqueous are prepared: 1.00 m Na2CO3 and 1.00 m LiCl. Which of the following statements is true?


A) The Na2CO3 solution has a higher osmotic pressure and higher vapor pressure than the LiCl solution.
B) The Na2CO3 solution has a higher osmotic pressure and higher boiling point than the LiCl solution.
C) The Na2CO3 solution has a lower osmotic pressure and lower vapor pressure than the LiCI solution.
D) The Na2CO3 solution has a lower osmotic pressure and higher boiling point than the LiCl solution.
E) None of these choices is correct.

F) D) and E)
G) None of the above

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Electrolyte solutions generally behave less ideally as the solute concentration increases.

A) True
B) False

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If a 100-mL sample of a volatile liquid such as diethyl ether is introduced into a 250-mL flask which is immediately sealed, the pressure inside will increase above atmospheric pressure. Explain.

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The pressure inside the flask will initi...

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Cadmium bromide is used in photography and lithography. Calculate the molality of a solution prepared by dissolving 45.38 g of CdBr2 in 375.0 g of water.


A) 0.03035 m
B) 0.01600 m
C) 0.1210 m
D) 0.4446 m
E) None of these choices is correct.

F) A) and E)
G) A) and D)

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Which of the following aqueous solutions should demonstrate the most non-ideal behavior?


A) 0.1 M NaI
B) 0.2 M CuSO4
C) 0.5 M KBr
D) 2.0 M CuCl2
E) 2.0 M CsCl

F) A) and E)
G) A) and B)

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Cinnamaldehyde (? = 132.15 g/mol) is used as a flavoring agent. What mass of cinnamaldehyde must be added to 175 g of ethanol to give a solution whose boiling point is 82.7 °\degree C? Kb = 1.22 °\degree C/m, boiling point of pure ethanol = 78.5 °\degree C


A) 62.4 g
B) 67.8 g
C) 76.2 g
D) 78.5 g
E) 79.6 g

F) A) and B)
G) A) and C)

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