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Which of the following elements has the largest atomic size?


A) S
B) Ca
C) Ba
D) Po
E) Rn

F) B) and E)
G) A) and B)

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The electronic structure 1s22s22p63s23p64s23d8 refers to the ground state of


A) Kr.
B) Ni.
C) Fe.
D) Pd.
E) None of these choices are correct.

F) A) and E)
G) B) and D)

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Which of the following electron configurations is correct for the excited state of an element?


A) [He]2 s 22 p 5
B) [Ne]3 s 23 p 1
C) [Ar]4 s 14 p 1
D) [Kr]5 s 24 d 7
E) [He]1 p 1

F) A) and D)
G) B) and D)

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Select the most acidic compound from the following.


A) SO 2
B) Al 2O 3
C) CaO
D) PbO
E) H 2O

F) A) and E)
G) A) and B)

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Bigger atoms generally have smaller ionization energies.

A) True
B) False

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In neutral atoms, the 3d orbitals have higher energy than the 4s orbitals.

A) True
B) False

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The most basic oxides are formed from elements found in the __________ region of the periodic table.


A) upper right
B) upper left
C) center
D) lower right
E) lower left

F) C) and E)
G) A) and C)

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In moving down a group in the periodic table, the oxides of the elements become more acidic in nature.

A) True
B) False

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In the ground state of an atom of silver (Ag) , how many electrons will there be with the quantum number l = 1? (The n, ml, and ms quantum numbers may have any appropriate values.)


A) 9
B) 12
C) 18
D) 24
E) 36

F) A) and E)
G) B) and E)

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Which of the following atoms will be diamagnetic?


A) Cr
B) Ru
C) Fe
D) Pt
E) Cd

F) None of the above
G) A) and D)

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In Mendeleev's version of the periodic table, the elements were arranged in order of increasing atomic number.

A) True
B) False

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An atom of element number 33 (As) is in its ground electronic state. Which one of the following sets quantum numbers could not apply to any of its electrons?


A) n = 2 l = 1 ml = −1 ms = +½
B) n = 3 l = 0 ml = 0 ms = −½
C) n = 3 l = 2 ml = −2 ms = −½
D) n = 4 l = 0 ml = 0 ms = −½
E) n = 4 l = 2 ml = 1 ms = +½

F) C) and D)
G) B) and E)

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The effective nuclear charge for an atom is less than the actual nuclear charge due to


A) shielding.
B) penetration.
C) paramagnetism.
D) electron-pair repulsion.
E) relativity.

F) D) and E)
G) B) and D)

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In many-electron atoms, which quantum numbers specify the energy of an electron?


A) n and l
B) n and ml
C) l and ml
D) n and ms
E) n, l, and ml

F) A) and E)
G) B) and C)

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Which of the following elements has the smallest atomic size?


A) Na
B) Ar
C) K
D) Ca
E) Kr

F) A) and B)
G) A) and C)

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Which of the following electron configurations is impossible?


A) 1 s 22 s 22 p 63 s 23 p 4
B) 1 s 22 s 22 p 53 s 13 p 4
C) 1 s 22 s 22p 63 s 23 p 63 d 104 s 2
D) 1 s 22 s 22 p 63 s 33 p 4
E) 1 s 12 s 22 p 63 s 23 p 4

F) B) and E)
G) All of the above

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Which one of the following equations correctly represents the process involved in the electron affinity of X?


A) X( g) → X +( g) + e
B) X +( g) → X +( aq)
C) X +( g) + e → X( g)
D) X( g) + e → X ( g)
E) X +( g) + Y ( g) → XY( s)

F) C) and D)
G) None of the above

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First ionization energies of neutral atoms may be positive or negative.

A) True
B) False

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Select the correct electron configuration for sulfur (Z = 16) .


A) 1 s 21 p 62 s 22 p 6
B) 1 s 22 s 22 p 83 s 23 p 4
C) 1 s 22 s 22 p 83 s 23 p 2
D) 1 s 22 s 22 p 63 s 23 p 4
E) 1 s 22 s 22 p 63 s 23 d 4

F) C) and D)
G) A) and B)

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How many valence electrons are there in an atom with the electron configuration [noble gas]ns2(n −1) d10np3?


A) 2
B) 3
C) 5
D) 10
E) 15

F) All of the above
G) A) and B)

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