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Cinnamaldehyde (ℳ = 132.15 g/mol) is used as a flavoring agent. What mass of cinnamaldehyde must be added to 175 g of ethanol to give a solution whose boiling point is 82.7°C? Kb = 1.22°C/m, boiling point of pure ethanol = 78.5°C


A) 62.4 g
B) 67.8 g
C) 76.2 g
D) 78.5 g
E) 79.6 g

F) C) and D)
G) B) and E)

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Which of the following pairs of ions is arranged so that the ion with the larger (i.e., more negative) heat of hydration is listed first?


A) Br , K +
B) Mg 2+, Sr 2+
C) Ca 2+, Sc 3+
D) Na +, Li +
E) None of these choices are correct.

F) C) and E)
G) A) and B)

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Calcium nitrite is used as a corrosion inhibitor in lubricants. What is the molality of a solution prepared by dissolving 18.5 g of calcium nitrite in 83.5 g of distilled water?


A) 0.0342 m
B) 0.0855 m
C) 0.222 m
D) 0.444 m
E) 1.68 m

F) A) and E)
G) D) and E)

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All solutions are mixtures

A) True
B) False

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A saturated solution of carbon dioxide in water contains 3.00 g of CO2 when the CO2 partial pressure is 8.0 atm. What mass of CO2 will escape if the partial pressure is lowered to 3.2 atm?


A) 0.90 g
B) 1.20 g
C) 1.40 g
D) 1.80 g
E) 2.20 g

F) All of the above
G) A) and B)

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Calculate the vapor pressure of a solution prepared by dissolving 0.500 mol of a non-volatile solute in 275 g of hexane (ℳ = 86.18 g/mol) at 49.6°C. P°hexane = 400.0 torr at 49.6°C.


A) 54 torr
B) 154 torr
C) 246 torr
D) 346 torr
E) 400. torr

F) A) and B)
G) A) and C)

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The chemist, Anna Lytic, must prepare 1.00 kg of 15.0% (w/w) acetic acid using a stock solution which is 36.0% (w/w) acetic acid (d = 1.045 g/mL) . Which of the following combinations will give her the solution she wants?


A) 417 mL of 36% acetic acid in 583 mL of distilled water
B) 417 g of 36% acetic acid in 583 g of distilled water
C) 360 mL of 36% acetic acid in 640 mL of distilled water
D) 360 g of 36% acetic acid in 640 g of distilled water
E) 150 g of 36% acetic acid in 850 g of distilled water

F) D) and E)
G) A) and D)

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Lysine is an amino acid that is an essential part of nutrition but which is not synthesized by the human body. What is the molar mass of lysine if 750.0 mL of a solution containing 8.60 g of lysine has an osmotic pressure of 1.918 atm? Temperature = 25.0°C


A) 110. g/mol
B) 146 g/mol
C) 220. g/mol
D) 1340 g/mol
E) 1780 g/mol

F) C) and D)
G) All of the above

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Which one of the following pairs of dispersed phases and dispersing media can never form a colloid?


A) Solid and Gas
B) Liquid and Gas
C) Solid and Solid
D) Liquid and Liquid
E) Gas and Gas

F) A) and B)
G) A) and E)

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Which of the following statements describes the correct method of preparation of 1.00 L of a 2.0 M urea solution? ℳurea = 60.06 g/mol


A) Dissolve 120 g of urea in 1.00 kg of distilled water.
B) Dissolve 120 g of urea in 880 g of distilled water.
C) Dissolve 120 g of urea in enough distilled water to produce 1.00 L of solution.
D) Dissolve 120 g of urea in 1.00 liter of distilled water.
E) The density of urea is needed in order to do this calculation.

F) D) and E)
G) A) and E)

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How many moles of solute particles are present in 100.0 mL of 2.50 M (NH4) 3PO4?


A) 0.100 mol
B) 0.250 mol
C) 0.500 mol
D) 0.750 mol
E) 1.00 mol

F) A) and D)
G) C) and E)

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When two pure substances are mixed to form a solution


A) heat is released.
B) heat is absorbed.
C) there is an increase in entropy.
D) there is a decrease in entropy.
E) entropy is conserved.

F) B) and E)
G) A) and E)

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What is the mole fraction of Ne in a mixture containing 10.1 g of Ne, 79.9 g of Ar, and 83.8 g of Kr?


A) 0.40
B) 0.25
C) 0.20
D) 0.14
E) 0.058

F) A) and E)
G) A) and D)

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Which of the following aqueous solutions should demonstrate the most ideal behavior?


A) 0.1 M K 2SO 4
B) 0.1 M CaCl 2
C) 3.0 M LiF
D) 0.1 M MgSO 4
E) 0.1 M NaCl

F) B) and E)
G) All of the above

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Potassium hydrogen phosphate is used in the preparation of nondairy powdered creamers. Calculate the molarity of a solution prepared by dissolving 238 g of K2HPO4 in enough water to produce 275 mL of solution.


A) 0.732 M
B) 0.865 M
C) 2.66 M
D) 4.97 M
E) None of these choices are correct.

F) A) and D)
G) All of the above

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Select the type of interaction that best describes the attraction between Mg2+ ions and water molecules.


A) dipole-dipole
B) dipole-induced dipole
C) ion-dipole
D) ion-induced dipole
E) ion-hydrogen bond

F) A) and C)
G) B) and D)

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