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Clearly state the thermodynamic standard state of a. an element or compound. b. a solute.

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a. Standard state is the stabl...

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If two solutions are mixed together in a container and the container "feels hot", then


A) the reaction is endothermic.
B) the reaction is exothermic.
C) the energy of the universe is increased.
D) the energy of both the system and the surroundings is decreased.
E) the energy of the system is increased.

F) A) and E)
G) C) and D)

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Given that CaO(s) + H2O(l) → Ca(OH) 2(s) , ΔH°rxn = -64.8 kJ/mol, how many grams of CaO must react in order to liberate 525 kJ of heat?


A) 6.92 g
B) 56.1 g
C) 454 g
D) 606 g
E) 3.40 × 104 g

F) C) and D)
G) A) and C)

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The standard temperature is ________; the standard concentration of a solution is ________; and the standard pressure is ________.

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usually 25...

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What is ΔH°rxn for the following reaction? C6H6(l) + 15/2 O2(g) → 6CO2(g) + 3H2O(l) 6C(graphite) + 3H2(g) → C6H6(l) ΔH°rxn = +49.0 kJ/mol C(graphite) + O2(g) → CO2(g) ΔH°rxn = -393.5 kJ/mol H2(g) + ½O2(g) → H2O(l) ΔH°rxn = -285.8 kJ/mol


A) -630.3 kJ/mol
B) -2597.8 kJ/mol
C) -3169.4kJ/mol
D) -3267.4 kJ/mol
E) 630.3 kJ/mol

F) A) and B)
G) A) and E)

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A 275-g sample of nickel at l00.0°C is placed in 100.0 g of water at 22.0°C. What is the final temperature of the water? Assume no heat transfer with the surroundings. The specific heat of nickel is 0.444 J/g·°C and the specific heat of water is 4.184 J/g·°C.


A) 39.6°C
B) 40.8°C
C) 61.0°C
D) 79.2°C
E) 82.4°C

F) A) and D)
G) B) and E)

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Atoms A and Z may form either single bonds or double bonds. Shown is an energy diagram for the formation of a single bond between A and Z from the individual atoms in the gas phase. Atoms A and Z may form either single bonds or double bonds. Shown is an energy diagram for the formation of a single bond between A and Z from the individual atoms in the gas phase.   Which diagram below corresponds to the reaction A(g)  + Z(g)  → A=Z(g) ? A)    B)    C)    D)    E)   Which diagram below corresponds to the reaction A(g) + Z(g) → A=Z(g) ?


A) Atoms A and Z may form either single bonds or double bonds. Shown is an energy diagram for the formation of a single bond between A and Z from the individual atoms in the gas phase.   Which diagram below corresponds to the reaction A(g)  + Z(g)  → A=Z(g) ? A)    B)    C)    D)    E)
B) Atoms A and Z may form either single bonds or double bonds. Shown is an energy diagram for the formation of a single bond between A and Z from the individual atoms in the gas phase.   Which diagram below corresponds to the reaction A(g)  + Z(g)  → A=Z(g) ? A)    B)    C)    D)    E)
C) Atoms A and Z may form either single bonds or double bonds. Shown is an energy diagram for the formation of a single bond between A and Z from the individual atoms in the gas phase.   Which diagram below corresponds to the reaction A(g)  + Z(g)  → A=Z(g) ? A)    B)    C)    D)    E)
D) Atoms A and Z may form either single bonds or double bonds. Shown is an energy diagram for the formation of a single bond between A and Z from the individual atoms in the gas phase.   Which diagram below corresponds to the reaction A(g)  + Z(g)  → A=Z(g) ? A)    B)    C)    D)    E)
E) Atoms A and Z may form either single bonds or double bonds. Shown is an energy diagram for the formation of a single bond between A and Z from the individual atoms in the gas phase.   Which diagram below corresponds to the reaction A(g)  + Z(g)  → A=Z(g) ? A)    B)    C)    D)    E)

F) A) and B)
G) All of the above

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The combustion of pentane produces heat according to the following thermochemical equation. C5H12(l) + 8O2(g) → 5CO2(g) + 6H2O(l) ΔH°rxn= -3510 kJ/mol How many grams of CO2 is produced per 2.50 × 103 kJ of heat released?


A) 6.27 g
B) 31.3 g
C) 61.8 g
D) 157 g
E) 220 g

F) C) and E)
G) A) and D)

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Pentaborane B5H9(s) burns vigorously in O2 to give B2O3(s) and H2O(l) . What is ΔH° for the combustion of 1 mol of B5H9(s) ? Substance ΔH°f (kJ/mol) B2O3(s) -1273.5 B5H9(s) +73.2 H2O(l) -285.8


A) -1.5 × 103 kJ
B) -1.6× 103 kJ
C) -4.4 × 103 kJ
D) -4.7× 103 kJ
E) -9.0× 103 kJ

F) B) and D)
G) A) and D)

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Using Hess's law, what is ΔH°rxn for the following reaction? NO(g) + O(g) → NO2(g) Using Hess's law, what is ΔH°<sub>rxn</sub> for the following reaction? NO(g)  + O(g)  → NO<sub>2</sub>(g)    A)  -839.8 kJ/mol B)  -306.0 kJ/mol C)  157.9 kJ/mol D)  394.9 kJ/mol E)  442.3 kJ/mol


A) -839.8 kJ/mol
B) -306.0 kJ/mol
C) 157.9 kJ/mol
D) 394.9 kJ/mol
E) 442.3 kJ/mol

F) B) and C)
G) A) and E)

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How much heat is required to raise the temperature of 22.8 g of copper from 20.0°C to 875.0°C? The specific heat of copper is 0.385 J/g·°C.


A) 14.4 J
B) 176 J
C) 7.51 kJ
D) 7.68 kJ
E) 9.90 kJ

F) C) and D)
G) B) and E)

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Cold packs, whose temperatures are lowered when ammonium nitrate dissolves in water, are carried by athletic trainers when transporting ice is not possible. Which of the following is true of this reaction?


A) ΔH< 0, process is exothermic
B) ΔH> 0, process is exothermic
C) ΔH< 0, process is endothermic
D) ΔH> 0, process is endothermic
E) ΔH = 0, since cold packs are sealed

F) C) and D)
G) C) and E)

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What is ΔH°rxn for the following reaction? NO2(g) + CO(g) → CO2(g) + NO(g) What is ΔH°<sub>rxn </sub>for the following reaction? NO<sub>2</sub>(g)  + CO(g)  → CO<sub>2</sub>(g)  + NO(g)    A)  339.6 kJ B)  379.8 kJ C)  -226.5 kJ D)  -339.6 kJ E)  -379.8 kJ


A) 339.6 kJ
B) 379.8 kJ
C) -226.5 kJ
D) -339.6 kJ
E) -379.8 kJ

F) D) and E)
G) A) and D)

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For which of the substances below is ΔHof = 0?


A) O2(g)
B) N2(l)
C) Na(g)
D) Xe(l)

E) A) and B)
F) None of the above

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Which equation has a ΔHrxn that is not equal to ΔHof of the product?


A) F2(g) + ½O2(g) → F2O(g)
B) O2(g) + 2H2(g) → 2H2O(g)
C) H2(g) + ½O2(g) + → H2O(l)
D) Ti(s) + 2Cl2(g) → TiCl4(l)
E) ½H2(g) + ½Cl2(g) → HCl(g)

F) None of the above
G) B) and D)

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When heat is absorbed by the system and work is done by the system on the surroundings then


A) q is negative and w is positive.
B) both q and w are positive.
C) both q and w are negative.
D) q is positive and w is negative.
E) both q and w are zero.

F) None of the above
G) C) and E)

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A system contracts from an initial volume of 15.0 L to a final volume of 10.0 L under a constant external pressure of 0.80 atm. What is w? (1 L·atm = 101.3 J)


A) -4.0 J
B) +4.0 J
C) -4.1 ×102 J
D) +4.1 ×102 J
E) +81 J

F) C) and D)
G) None of the above

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A 307-g sample of an unknown mineral was heated to 98.7°C and placed into a calorimeter containing 72.4 g of water at 23.6°C. The heat capacity of the calorimeter was 15.7 J/°C. The final temperature in the calorimeter was 32.4°C. What is the specific heat capacity of the mineral?


A) 0.124 J/g·°C
B) 0.131 J/g·°C
C) 0.138 J/g·°C
D) 0.145 J/g·°C
E) None of these choices is correct.

F) A) and E)
G) A) and D)

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A glass containing 200.0 g of H2O at 20.0°C was placed in a refrigerator. The water loses 11.7 kJ of heat as it cools to a constant temperature. What is its new temperature? The specific heat of water is 4.184 J/g·°C.


A) 0.0°C
B) 4.0°C
C) 6.0°C
D) 14.0°C
E) 34.0°C

F) All of the above
G) A) and B)

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Suppose a new metallic element X is discovered, and its reactions with oxygen gas and chlorine gas at 298 K are studied. Suppose a new metallic element X is discovered, and its reactions with oxygen gas and chlorine gas at 298 K are studied.   However, it is later discovered that one of the samples was contaminated, and the ΔHº<sub>rxn</sub> value from this trial is not reliable. Which trial had the contaminated sample, and what should the correct value of ΔHº<sub>rxn</sub> be for this trial? A)  Trial 1 had the contaminated sample; its ΔHº<sub>rxn</sub> value should be -900 kJ/mol. B)  Trial 2 had the contaminated sample; its ΔHº<sub>rxn</sub> value should be +100 kJ/mol. C)  Trial 3 had the contaminated sample; its ΔHº<sub>rxn</sub> value should be -1000 kJ/mol. D)  Trial 3 had the contaminated sample; its ΔHº<sub>rxn</sub> value should be +1000 kJ/mol. E)  Not enough information is provided; all three trials must be redone. However, it is later discovered that one of the samples was contaminated, and the ΔHºrxn value from this trial is not reliable. Which trial had the contaminated sample, and what should the correct value of ΔHºrxn be for this trial?


A) Trial 1 had the contaminated sample; its ΔHºrxn value should be -900 kJ/mol.
B) Trial 2 had the contaminated sample; its ΔHºrxn value should be +100 kJ/mol.
C) Trial 3 had the contaminated sample; its ΔHºrxn value should be -1000 kJ/mol.
D) Trial 3 had the contaminated sample; its ΔHºrxn value should be +1000 kJ/mol.
E) Not enough information is provided; all three trials must be redone.

F) A) and D)
G) A) and C)

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