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Which of the following substances has the greatest solubility in water?


A) PbI2,Ksp = 7.9 ×\times 10-9
B) BaF2,Ksp = 1.5 ×\times 10-6
C) Ca(OH) 2,Ksp = 6.5 ×\times 10-6
D) Zn(IO3) 2,Ksp = 3.9 ×\times 10-6
E) Ag2SO4,Ksp = 1.5 ×\times 10-5

F) C) and D)
G) A) and E)

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A lab technician adds 0.20 mol of NaF to 1.00 L of 0.35 M cadmium nitrate,Cd(NO3) 2.Which of the following statements is correct? Ksp = 6.44 ×\times 10-3 for CdF2


A) Cadmium fluoride precipitates until the solution is saturated.
B) The solution is unsaturated and no precipitate forms.
C) The solubility of cadmium fluoride is increased by the presence of additional fluoride ions.
D) One must know Ksp for cadmium nitrate to make meaningful predictions on this system.
E) The presence of NaF will raise the solubility of Cd(NO3) 2.

F) A) and E)
G) B) and E)

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When a strong acid is titrated with a strong base,the pH at the equivalence point


A) is greater than 7.0.
B) is equal to 7.0.
C) is less than 7.0,but is not 3.5.
D) is equal to the pKa of the acid.
E) is equal to 3.5.

F) C) and D)
G) A) and C)

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What is the pH of a buffer that consists of 0.20 M NaH2PO4 and 0.40 M Na2HPO4? Ka = 6.2 ×\times 10-8


A) 6.51
B) 6.91
C) 7.51
D) 7.90
E) 8.13

F) A) and E)
G) B) and C)

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Calculate the solubility of barium carbonate,BaCO3,in pure water.Ksp = 2.0 ×\times 10-9


A) 1.3 ×\times 10-3 M
B) 3.2 ×\times 10-5 M
C) 2.2 ×\times 10-5 M
D) 4.5 ×\times 10-5 M
E) 4.0 ×\times 10-18 M

F) B) and C)
G) A) and B)

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Which of the following has the highest buffer capacity?


A) 0.10 M H2PO4-/0.10 M HPO42-
B) 0.50 M H2PO4-/0.10 M HPO42-
C) 0.10 M H2PO4-/0.50 M HPO42-
D) 0.50 M H2PO4-/0.50 M HPO42-
E) They all have the same buffer capacity.

F) A) and C)
G) A) and D)

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Which of the following acids should be used to prepare a buffer with a pH of 4.5?


A) HOC6H4OCOOH,Ka = 1.0 ×\times 10-3
B) C6H4(COOH) 2,Ka = 2.9 ×\times 10-4
C) CH3COOH,Ka = 1.8 ×\times 10-5
D) C5H5O5COOH-2,Ka = 4.0 ×\times 10-6
E) HBrO,Ka = 2.3 ×\times 10-9

F) A) and B)
G) A) and C)

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The end point in a titration is defined as the point when the indicator changes color.

A) True
B) False

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A formic acid buffer containing 0.50 M HCOOH and 0.50 M HCOONa has a pH of 3.77.What will the pH be after 0.010 mol of NaOH has been added to 100.0 mL of the buffer?


A) 3.67
B) 3.78
C) 3.81
D) 3.85
E) 3.95

F) C) and D)
G) D) and E)

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Calculate the solubility of lead(II) iodide,PbI2,in 0.025 M KI.Ksp = 7.9 ×\times 10-9


A) 4.5 ×\times 10-2 M
B) 2.8 ×\times 10-2 M
C) 8.9 ×\times 10-5 M
D) 5.0 ×\times 10-5 M
E) 1.3 ×\times 10-5 M

F) None of the above
G) C) and E)

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When a weak acid is titrated with a strong base,the pH at the equivalence point


A) is greater than 7.0.
B) is equal to 7.0.
C) is less than 7.0.
D) is equal to the pKa of the acid.
E) is equal to 14.0 - pKb ,where pKb is that of the base.

F) A) and B)
G) None of the above

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At the equivalence point in an acid-base titration


A) the [H3O+] equals the Ka of the acid.
B) the [H3O+] equals the Ka of the indicator.
C) the amounts of acid and base which have been combined are in their stoichiometric ratio.
D) the pH is 7.0.
E) the pH has reached a maximum.

F) A) and B)
G) C) and D)

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What will be the effect of adding 0.5 mL of 0.1 M HCl to 100 mL of a phosphate buffer in which [H2PO4-] = [HPO42-] = 0.35 M?


A) The pH will increase slightly.
B) The pH will increase significantly.
C) The pH will decrease slightly.
D) The pH will decrease significantly.
E) Since it is a buffer solution,the pH will not be affected.

F) B) and E)
G) A) and B)

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Which of the following substances has the greatest solubility in water?


A) Ba(IO3) 2,Ksp = 1.5 ×\times 10-9
B) PbF2,Ksp = 3.6 ×\times 10-8
C) SrSO4,Ksp = 3.2 ×\times 10-7
D) CuCl,Ksp = 1.9 ×\times 10-7
E) CdS,Ksp = 1.0 ×\times 10-24

F) B) and D)
G) A) and C)

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Which of the following aqueous mixtures would be a buffer system?


A) HCl,NaCl
B) HNO3,NaNO3
C) H3PO4,H2PO4-
D) H2SO4,CH3COOH
E) NH3,NaOH

F) C) and D)
G) B) and D)

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What is the [H3O+] in a solution that consists of 0.15 M C2N2H8(ethylene diamine) and 0.35 C2N2H9Cl? Kb = 4.7 ×\times 10-4


A) 2.0 ×\times l0-3 M
B) 1.1 ×\times 10-3 M
C) 6.3 ×\times 10-9 M
D) 2.1 ×\times 10-10 M
E) 5.0 ×\times 10-11 M

F) B) and C)
G) C) and D)

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